I just learned (from Emmanuel Kowalski’s blog) that the AMS has just started a repository of open-access mathematics lecture notes. There are only a few such sets of notes there at present, but hopefully it will grow in the future; I just submitted some old lecture notes of mine from an undergraduate linear algebra course I taught in 2002 (with some updating of format and fixing of various typos).
[Update, Dec 22: my own notes are now on the repository.]